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|Title||Reaction of Nitrilimines with 2-Substituted Aza-heterocycles. Synthesis of Pyrrolo [1, 2-a] pyridine and Pyrimido [2, 1-d] 1, 2, 3, 5-tetrazine|
The reaction of nitrilimine 6a with ethyl pyridine-2-acetate (7) gave the corresponding pyrrolo [1, 2-a] pyridine 8, while the reaction of 6b containing an ester moiety afforded the acyclic adduct 9. The reaction of 6a with 2-aminopyrimidine (10) gave the novel unexpected pyrimido [2, 1-d] 1, 2, 3, 5-tetrazine 11. Acyclic adducts 16 and 17 were obtained from the reaction of 6b with 2-cyanomethylbenzimidazole (14) and 2-aminobenzimidazole (15), respectively.
|Series||Volume: 13, Number: 1|
|Publisher||Molecular Diversity Preservation International|
|Item link||Item Link|
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