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Title | Synthesis of Dihydro-and Tetrahydro-1, 2, 4, 5-tetrazines from the Reaction of Nitrilimines with 1-Substituted-1-methylhydrazine |
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Untitled | |
Abstract |
The reaction of nitrilimines (2) with 1-substituted-1-methylhydrazines (3–6) led to the formation of the respective amidrazones (7) when R = CH3, Ph, and to the acyclic adducts (8,9) when R = CHO and COCH3. The acyclic adducts underwent thermal oxidative cyclization at CH3 to give the unexpected 1,2,4,5-tetrazines (10,11). Dihydro-l,2,4,5-tetrazines (12) were also seperated when R = CHO. |
Type | Journal Article |
Date | 2003 |
Published in | Synthetic communications |
Series | Volume: 33, Number: 8 |
Publisher | Taylor & Francis Group |
Citation | |
Item link | Item Link |
License | ![]() |
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