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http://hdl.handle.net/20.500.12358/26165
Title | Synthesis and structure of 2-aryl-5, 5-disubstituted-1, 3-dioxanes and conversion into chiral (1, 1, 1-trishydroxymethyl) methane derivatives |
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Untitled | |
Abstract |
Pentaerythritol, (1,1,1-trishydroxymethyl)methyl methane and (1,1,1-trishydroxymethyl)nitromethane are converted into 2-aryl-5,5-bis(hydroxymethyl), 2-aryl-5-hydroxymethyl-5-methyl- or 2-aryl-5-hydroxymethyl-5-nitro-1,3-dioxanes and a range of derivatives. X-Ray and NMR analysis establishes that the latter is obtained as a single diastereomer whose structure is unambiguously determined. These materials can be elaborated to chiral derivatives of the starting (1,1,1-trishydroxymethyl) methanes. |
Type | Journal Article |
Date | 2002 |
Published in | Tetrahedron letters |
Series | Volume: 43, Number: 11 |
Publisher | Pergamon |
Citation | |
Item link | Item Link |
License | ![]() |
Collections | |
Files in this item | ||
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Morjan, Rami Y._2.pdf | 173.6Kb |